Kreitler and others (1983) categorized the formation waters of the
East Texas basin into two broad groupsshallow formations (Woodbine,
Eagle Ford, and Nacatoch) and deeper formations (Glen Rose and Travis
Peak). The Paluxy Formation is transitional between these two groups
in terms of depth, water chemistry, and rock / water reaction. "The
ionic solutes in the deep-basin brines result initially from the
dissolution of salt domes by meteoric ground water" (Kreitler
and others, 1983, p. 84). Kreitler and others interpreted the Na
and Cl in the brines to come from the dissolution of salt domes
in the basin throughout geologic time. Therefore, the Na/Cl molar
ratio of approximately 1 in the shallower formations "indicates
minimal water-rock interactions." Conversely, the brines in
the deeper formations have a Na/Cl molar ratio of approximately
0.7. "The increase in calcium . . . and loss of Na . . . are
attributed to albitization. In this reaction, sodium in solution
is exchanged for calcium in the plagioclase" (Kreitler and
others, 1983, p. 88). Furthermore, the Paluxy is the first formation
in which the higher Ca concentrations are encountered with increasing
depth (Kreitler and others, 1983, p. 71). Similarly, Kreitler and
others noted an increase in potassium concentration with depth,
which they attributed to the dissolution of K-feldspars or the transformation
of ("albitization") K-feldspars to albite. Therefore,
the waters of the deeper formations, including to some degree the
Paluxy, are Na-Ca-Cl type waters that have evolved form Na-Cl waters
(Kreitler and others, 1983, p. 67). Immature sandstone composition
and high-Ca brine suggest moderate potential for rock/water reaction
with injection of CO2.
13
Reference:
Kreitler,
C. W., Collins, E. W., Fogg, G. E., Jackson, M., and Seni, S. J.,
1983, Hydrogeologic characterization of the saline aquifers, East
Texas Basin: implications to nuclear waste storage in East Texas
salt domes: The University of Texas at Austin, Bureau of Economic
Geology, report prepared for U.S. Department of Energy under contract
no. DE-AC97-80ET46617.