2.Jackson School of Geosciences, Bureau of Economic Geology, The University of Texas at Austin, University Station, Box X, Austin, TX 78713-8924, USA

In order to safely store CO₂ in depleted reservoirs and deep saline aquifers, a better understanding of the storage mechanisms of CO₂ is needed. Reaction of CO₂ with minerals to form precipitate in the subsurface helps to securely store CO₂ over geologic time periods, but a concern is the formation of localized channels through which CO₂ could travel at large, localized rates. Pore-scale network modeling is an attractive option for modeling and understanding this inherently pore-level process, but the relatively small domains of pore-scale network models may prevent accurate upscaling. Here, we develop a transient, single-phase, reactive pore-network model that includes reduction of throat conductivity as a result of precipitation. The novelty of this study is the implementation of a new mortar/transport method for coupling pore networks together at model interfaces that ensure continuity of pressures, species concentrations, and fluxes. The coupling allows for modeling at larger scales which may lead to more accurate upscaling approaches. Here, we couple pore-scale models with large variation in permeability and porosity which result in initial preferential pathways for flow. Our simulation results suggest that the preferential pathways close due to precipitation, but are not redirected at late times.